alkA Family assigned · medium auto-curated

H37Rv Rv1317c · MTBC0 mtbc0_001412 · 496 aa · 1486656–1488146 (-) · RefSeq NP_215833.1

Annotation: from legacy to revised

Legacy (H37Rv / Mycobrowser)bifunctional regulatory protein/DNA repair enzyme AlkA
MTBC0 PGAP re-annotationbifunctional regulatory protein/DNA repair enzyme AlkA
Revised (this work)Bifunctional regulatory protein/DNA repair enzyme AlkA. Pfam: Ada_Zn_binding (PF02805.22), HTH_18 (PF12833.14), AlkA_N (PF06029.18), HhH-GPD (PF00730.32).

Auto-curated: this verdict and function were generated by rules from PGAP + Pfam + Foldseek and have not been hand-reviewed.

Curated reference (UniProt)

UniProt P9WJW3 SwissProt · reviewed · Evidence at protein level
UniProt nameProbable bifunctional transcriptional activator/DNA repair enzyme AlkA
EC (curated) EC 2.1.1.n11, EC 3.2.2.21
Curated functionIs involved in the adaptive response to alkylation damage in DNA caused by alkylating agents. Repairs the Sp diastereomer of DNA methylphosphotriester lesions by a direct and irreversible transfer of the methyl group to one of its own cysteine residues. Also catalyzes the hydrolysis of the deoxyribose N-glycosidic bond to excise 3-methyladenine, 3-methylguanine, 7-methylguanine, O2-methylthymine, and O2-methylcytosine from the damaged DNA polymer formed by alkylation lesions (By similarity)..; FUNCTION: The methylation of Alka by methylphosphotriesters in DNA leads to its activation as a trans.

Functional vocabulary (eggNOG-mapper, orthology transfer)

COG category K Transcription
Preferred namealkA
eggNOG descriptioninvolved in damage reversal and in base excision repair. the methylated Ada protein acts as a positive regulator of its own synthesis, as well as that of other proteins. the transcription-activating function of the Ada protein resides in its N-terminus. repair of alkylated guanine in DNA by stoichiometrically transferring the alkyl group at the O-6 position to a cysteine residue in the enzyme. this is a suicide reaction the enzyme is irreversibly inactivated. can also repair O-4- methylthymine catalytic activity DNA (containing 6-O- methylguanine) protein -L-cysteine DNA (without 6-O- methylguanine) protein S-methyl-L-cysteine
Orthologous groupCOG0122
EC number EC 3.2.2.21
KEGG orthology K13529
KEGG pathways map03410
Gene Ontology (60) GO:0003674, GO:0003676, GO:0003677, GO:0003684, GO:0003824, GO:0003905, GO:0005488, GO:0005575, GO:0005618, GO:0005622, GO:0005623, GO:0005737 +48 more

Orthology-based transfer (eggNOG 5.0.2, diamond). EC/KO/GO/CAZy are computed annotations, not manual curation; cross-check against the primary literature before treating a specific reaction as established.

Conservation & selection (intra-MTBC, 145 209 strains) pseudogene candidate

pN/pS 0.369 · purifying
Polymorphic sites (≥ 0.1% of strains) 7 synonymous, 6 missense, 1 nonsense, 1 frameshift
Disruption 2 distinct premature-stop/frameshift site(s); most common in 5.26% of strains (7645) · clonal

pN/pS from segregating SNPs (singletons removed) normalised by possible sites. Low pN/pS = purifying selection (a strong signal that a "hypothetical" is a real, constrained gene). A high pN/pS is ambiguous: relaxed constraint or positive selection (drug resistance, antigenic variation) inflate it; e.g. rpoB/katG/pncA score high here for resistance, not loss of function. A clonal disruption (one allele over a clade) suggests lineage pseudogenisation; a convergent one (many independent alleles) is typical of resistance loss-of-function.

Domains (Pfam, hmmscan --cut_ga)

PfamAccessioni-EvalueResiduesDescription
Ada_Zn_bindingPF02805.22 3.9e-288–71 Metal binding domain of Ada
HTH_18PF12833.14 3.8e-15106–185 Helix-turn-helix domain
AlkA_NPF06029.18 1.6e-35202–316 AlkA N-terminal domain
HhH-GPDPF00730.32 7.0e-06322–470 HhH-GPD superfamily base excision DNA repair protein

Functional interaction network (STRING v12, guilt-by-association)

Closest characterised functional partner: ogt (methylated-DNA--protein-cysteine methyltransferase), high confidence from genomic context alone (score 954 excluding text-mining).

PartnerProductScoreNo text-miningChannels (≥400)
Rv1316c ogt methylated-DNA--protein-cysteine methyltransferase 987 954 ctx neighborhood:881 coexpression:567 textmining:742
Rv1318c adenylate cyclase 785 786 ctx neighborhood:786
Rv0427c xthA exodeoxyribonuclease III protein XthA 894 759 database:651 textmining:579
Rv1321 nucS endonuclease NucS 715 682 ctx neighborhood:678
Rv1322 hyp hypothetical protein 648 649 ctx neighborhood:588
Rv3394c hyp hypothetical protein 664 549
Rv1631 coaE dephospho-CoA kinase CoaE 546 547 ctx neighborhood:544
Rv1998c hyp hypothetical protein 546 546 ctx cooccurence:404
Rv1307 atpH ATP synthase subunit b/delta 544 544 ctx neighborhood:544
Rv1319c adenylate cyclase 488 488 ctx neighborhood:488
Rv2737c recA recombinase A 860 473 textmining:746
Rv1537 dinX DNA polymerase IV 917 440 textmining:859
Rv1650 pheT phenylalanine--tRNA ligase subunit beta 438 439 ctx neighborhood:425
Rv3056 dinP DNA polymerase IV 2 810 438 textmining:677
Rv1320c adenylate cyclase 429 429 ctx neighborhood:429

STRING combines evidence channels (neighborhood, fusion, cooccurrence, coexpression, experimental, database, text-mining) into a 0–1000 score. The ctx badge marks edges carried by the genomic-context channels (conserved neighborhood, fusion, phylogenetic co-occurrence), which are independent of orthology and structure and the strongest signal for an unknown gene. The no text-mining column recomputes the score from data alone, so a link that does not depend on the literature is visible. Association is a function hypothesis, not proof: corroborate with the operon context and the primary literature before assigning a function.

Evidence

  • Legacy H37Rv annotation: bifunctional regulatory protein/DNA repair enzyme AlkA
  • MTBC0 PGAP product: bifunctional regulatory protein/DNA repair enzyme AlkA
  • Pfam (hmmscan --cut_ga): Ada_Zn_binding PF02805.22 (E=4e-28), HTH_18 PF12833.14 (E=4e-15), AlkA_N PF06029.18 (E=2e-35), HhH-GPD PF00730.32 (E=7e-06)
  • (auto-curated by rules from PGAP + Pfam + Foldseek; not hand-reviewed)

Sources

  • Ancestral sequence & coordinates: Harrison LB et al. (2024), An imputed ancestral reference genome for the MTBC, doi:10.1101/2023.09.07.556366
  • Product annotation: NCBI PGAP on MTBC0; legacy from H37Rv NC_000962.3 (RefSeq NP_215833.1)
  • Domains: Pfam-A via hmmscan --cut_ga — Ada_Zn_binding (PF02805.22), HTH_18 (PF12833.14), AlkA_N (PF06029.18), HhH-GPD (PF00730.32)
  • Sequence-level signal: ESM Atlas (EvolutionaryScale × BioHub) — exploratory
  • Controlled vocabulary: eggNOG-mapper 2.1.12 (Cantalapiedra et al. 2021, doi:10.1093/molbev/msab293), eggNOG 5.0 DB (Huerta-Cepas et al. 2019) — OG COG0122
  • Curated reference: UniProt P9WJW3 (SwissProt, reviewed; Evidence at protein level)
  • Intra-MTBC selection: pN/pS and disruption from SPDI variants of 145 209 MTBC strains (this work, local collection vs H37Rv NC_000962.3)
  • Interaction network: STRING v12.0 (Szklarczyk et al. 2023, doi:10.1093/nar/gkac1000), taxon 83332, CC-BY 4.0 — 54 functional partner(s); context anchor ogt
  • Primary literature: none located yet; annotation rests on the domain/homology sources above.

Ancestral MTBC0 protein sequence

>mtbc0_001412|Rv1317c|alkA
MHDDFERCYRAVQSKDARFDGWFVVAVLTTGVYCRPSCPVRPPFARNVRFLPTAAAAQGEGFRACKRCRPDASPGSPEWNVRSDVVARAMRLIADGTVDRDGVSGLAAQLGYTIRQLERLLQAVVGAGPLALARAQRMQTARVLIETTNLPFGDVAFAAGFSSIRQFNDTVRLACDGTPTALRARAAARFESATASAGTVSLRLPVRAPFAFEGVFGHLAATAVPGCEEVRDGAYRRTLRLPWGNGIVSLTPAPDHVRCLLVLDDFRDLMTATARCRRLLDLDADPEAIVEALGADPDLRAVVGKAPGQRIPRTVDEAEFAVRAVLAQQVSTKAASTHAGRLVAAYGRPVHDRHGALTHTFPSIEQLAEIDPGHLAVPKARQRTINALVASLADKSLVLDAGCDWQRARGQLLALPGVGPWTAEVIAMRGLGDPDAFPASDLGLRLAAKKLGLPAQRRALTVHSARWRPWRSYATQHLWTTLEHPVNQWPPQEKIA